Nano Carbon: A Happy Medium for Energy Storage

Although lithium-ion batteries seem to grab most of the headlines these days, lead-acid has long been the go-to chemistry for renewable energy storage. Despite their size and weight, lead-acid batteries can deliver large amounts of power at a reasonable price per kWh.

Lead-Acid Battery

 

Lead-Acid batteries are still the most common form of energy storage for photovoltaic systems. A lead-acid battery charges, stores, and discharges energy based on a chemical reaction of the metal that makes up the plates. The plates are in an acid that serves as the electrolyte to provide electrons that participate in the reactions. Lead-acid batteries can be easily recycled (99% of lead from used batteries is reclaimed) The reactions are as follows:

O2 + 2Pb → 2PbO

Pb + H2SO4- → PbSO4 + H+ + 2e-

PbO2 + HSO4- + 3H+ +e- → PbSO4 + 2H2O

:

These are reversible reactions that proceed in one direction when the battery is charging and in the other when it is discharging. The battery cycles by proceeding back and forth through these reactions repeatedly. The more times that the battery goes through these cycles, the more the state of health of the battery gradually deteriorates. Most batteries are considered to be at their end of life when they reach 80% of their initial, fully charged amp hour (Ah) capacity.

To incorporate larger quantities of intermittent renewable energy resources, tomorrow’s electric grid will require far more energy storage capacity. Traditionally, lead-acid batteries have been reserved for backup power and off-grid applications. This is in part due to the cycling limitations of the lead-acid chemistry. As a battery cycles from a charged to discharged state, and then back to fully charged state, lead and lead dioxide react with sulfuric acid within the battery, producing lead sulfate. This process is known as sulfation. Over time these crystalline sulfate deposits accumulate on the negative electrodes in the battery, thereby preventing the battery from returning to a full state of charge. Sulfation is exacerbated by high current discharge from a partial state of charge, a common ask of grid-scale energy storage.

Carbon Lead-Acid: A Battery To Meet Demand

Are lead-acid batteries forever relegated to small off-grid and residential applications? Not anymore. In 1997, research uncovered that by adding carbon to the negative electrodes of a battery dramatically decreases the degree of sulfation. Improvements to battery performance under high-rate partial-state-of-charge operation is also another benefit of carbon integration. Altogether, this means more cycles and a longer service life. 

 


Graph from GS Battery detailing improved cycle life of carbon lead-acid batteries over standard lead-acid batteries.

One manufacturer to embrace this technology is GS Battery. At 70% depth of discharge, the GS SLR-1000 achieves 5000 cycles. These qualities make the GS battery a good choice for both battery backup and off-grid solar applications. Carbon can be incorporated into the lead-acid design in a couple different configurations. One technique involves blending carbon additives into the lead sulfate paste that makes up the negative electrodes. Alternatively, electrodes can be partially replaced with the addition of a carbon-based electrochemical capacitor. This hybrid design greatly improves cycle life over traditional lead-acid batteries. 

Comments

Can you tell me about the end of life of these batteries? I have heard that are more easily recycleable than lithium-ion but I am not sure to what extent. A home owner customer of mine is very concerned about how recyclable the batteries are that I am thinking about and I want to be able to provide a solid explanation. Thanks in advance.  

Jack,

Simply put, scrap lead has a spot value of about $0.15 per pound ( http://www.scrapmsc.com/our-pricing/ ). The plastic and sulphuric acid are fully recoverable and can be used in new batteries after recycling. East Penn, a very large battery manufacturer, can even trap the sulphuric acid fumes and convert them to a usable ferilizer product with their advanced recovery process.

While chemistries like Lithium Iron Phosphate and others are theoretically recyclable, there is not the established scrap value chain. In fact, all other chemistries that I know of (excluding Aquion) are considered hazardous waste and have a disposal cost.

Here's a useful illustration from East Penn: http://www.dekabatteries.com/assets/base/recycling/recycling1.htmlhttp://www.dekabatteries.com/assets/base/recycling/recycling1.html

 

I think as a battery cycles from a charged to released state, and afterward back to completely charged state, lead and lead dioxide respond with sulfuric corrosive inside the battery, creating lead sulfate.